1-[(Z)-2-Phenylhydrazin-1-ylidene]-1-(piperidin-1-yl)propan-2-one
نویسندگان
چکیده
منابع مشابه
1-[(Z)-2-Phenylhydrazin-1-ylidene]-1-(piperidin-1-yl)propan-2-one
A Z configuration about the imine bond [1.3025 (18) Å] in the title compound, C(14)H(19)N(3)O, allows for the formation of an intra-moleclar N-H⋯N hydrogen bond between the hydrazone H and piperidine N atoms; the carbonyl group is disposed to lie over the piperidine residue, which is in a chair form. A twist between the terminal benzene ring and the hydrazine residue is seen [N-N-C-C torsion an...
متن کاملMethyl 1-[(Z)-2-(benzyloxycarbonyl)hydrazin-1-ylidene]-5-chloro-2-hydroxyindane-2-carboxylate
The title compound, C19H17ClN2O5, is an important inter-mediate for the synthesis of the pesticide Indoxacarb [systematic name: (S)-methyl 7-chloro-2-{[(meth-oxy-carbon-yl)[4-(tri-fluoro-meth-oxy)phen-yl]amino]-carbon-yl}-2H,3H,4aH,5H-indeno-[1,2-e][1,3,4]oxadiazine-4a-carboxyl-ate] The C=N double bond has a Z conformation. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal structure...
متن کامل(Z)-3-(2-Aminoanilino)-1-phenylbut-2-en-1-one
In the title compound, C16H16N2O, the phenyl and 2-amino-phenyl rings are almost perpendicular to one another, with a dihedral angle of 82.77 (8)°. There is an intra-molecular N-H⋯O hydrogen bond in the mol-ecule. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds forming chains along [001]. There are also C-H⋯π inter-actions present, linking the chains to form a three-dimensional s...
متن کامل(Z)-3-(2-Methoxyanilino)-1-phenylbut-2-en-1-one
In the title compound, C(17)H(17)NO(2), the dihedral angle between the two benzene rings is 55.2 (2)°. The meth-oxy group is slightly twisted away from the aniline ring [dihedral angle = 10.3 (2)°]. An intra-molecular N-H⋯O inter-action is present. In the crystal, the mol-ecules are linked into a three-dimensional supra-molecular network through two sets of C-H⋯π inter-actions.
متن کامل3,5a,9-Trimethyl-8-(2-phenylhydrazin-1-ylidene)-4,5,5a,9b-tetrahydro-3aH,8H-naphtho[1,2-b]furan-2(3H)-one
The title compound, C(21)H(24)N(2)O(2), is a phenyl hydrazine derivative of the well known anthelminthic agent α-santonin, which is composed of three fused rings (benzodieneone, cyclo-hexane and γ-lactone). The cyclo-hexa-dienone ring adopts a boat conformation, the cyclo-hexane ring is in a chair conformation and the trans-fused γ-lactone ring adopts a C-envelope conformation. In the crystal, ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811029680